All of your keys and passwords are the same for Steemit and Hive. You can see all keys when you log in with master password and go to wallet/permissions (on either steemit or hive.blog). Private posting key is used for posting and voting while private active is for transactions, voting witnesses etc. It's best to avoid using master pass and use only those 2 keys. Hope this helps. :)
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I shall try again! Maybe because I didn't sign into hive with the right one, it won't show me my hive passwords, as I can see them on Steemit, but IF they are the same, then great. I'll try using the the 'private active' for @curie witness, thanks for being patience with my ignorance :)