I don't think so that there is any specific time to post on steemit. Since this platform is used all over the world and one can upvote any time before expiry of 7 days. So the post remains available for the whole community for 7 days.
In my point of view if your post has the quality content then it will attract the audience automatically.
However, there is a possibility that if you are posting for a certain community then by following time zone of that community may earn some extra visibility.
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