Werner Heisenberg was the greatest German scientits for me. He worked close with the Danish scientist Niels Bohr while discovering the Quantum Theory. Other importan physicists were Carl Friedrich von Weizsäcker, anti-war acitivist and brother of the German President Richard von Weizsäcker, and Erwin Schrödinger whose theoretical cat is well known through popular science. :)
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Some great scientists indeed, thanks @orionvk - Erwin was new to me so second thanks!