The Weird Physics of a Supercooled Liquid at Temperature below 41 Degree Celsius

in #stemng7 years ago

Well, here is some cold facts that you may be interested in about cold. Nice play on words right there.

How cold is the coldest bottle of drink or water you had last time? If it was so cold, it set your teeth on edge with ice on it, that would be said to be an icy drink. So you could have had a drink at temperature of 0-degree Celcius




[Wikipedia]Source


The temperature at which water turns to ice is 0 degrees Celsius (32 degrees Fahrenheit) and below. But that is not always true for water can be a liquid and still cooled below 0-degree Celcius. Even though water freezes at 0 degree Celsius that is not its coldest form as a liquid. Water indeed has some weird property.

Scientists have been able to supercool water down to a temperature of around 229 Kelvin. That is about -45 degrees Celsius or -50 Fahrenheit.

If some conditions are in place, the researchers have demonstrated their ability to push the limit of cool on a liquid without its freezing as it usually does at 0 degrees Celsius.

One of the conditions for not freezing at 0 degrees Celsius is that the water would be extremely pure and free of seeds for ice crystallisation.

For water to freeze, it requires forming a small nucleus called seed that enables the molecules to create crystals. But water free from these nuclei can get extremely cold and not form crystals.


The Cooling Experiment



The thermodynamics of temperature or absolute temperature is that theoretical temperature at which the particles of matter is at its lowest energy or ground state. This is the state of minimal movement of particle constituent and the point it can no longer get colder.

At the absolute zero state, there are zero kinetic energy of particles which constitutes the matter. The temperature of a matter is dependent on the kinetic energy of its molecules. The faster they move, the higher the temperature. The slower they move, the lower the temperature.

That brings us to freezing. If the water kinetic energy slows down so much, it begins to attract the neighbouring molecules to form a crystal. Water that is below 0 degree Celsius in default mode freezes.

The researchers needed to walk around this default state of water.


The X-ray Probe to the Rescue


The scientists have this knowledge of supercooling water well below 0 degrees Celsius without its freezing. Scientists can push water to the -38 degrees Celsius, but the extreme crystallisation that follows makes studying its structural information as a liquid and getting reliable information impossible at below this point.

To bypass this no man's land the scientific team made use of an X-ray laser called LCLS (Linac Coherent Light Source) to measure the structure of the water drops.


Probing the water


The liquid injector shoots liquid water into a vacuum chamber. The water is rapidly evaporated bringing about cooling. Some of the droplets form into ice, but some remain as a liquid to and can be studied.

As the water is injected, it passes through an X-ray laser emitting pulses at the extremely rapid rate of 50 femtoseconds or 50 quadrillionths of a second. The scientist can now adjust the water temperature by changing the travel time of the droplets before the X-ray laser hits it.

The scientist can now study the diffraction of the pulses of the supercooled water droplets (cooled up to 229 Kelvin) to check the structural composition of the droplets.

That means the scientists has successfully entered into the no man's land of a supercooled liquid and also being able to check the molecular structure of the water.


Relevance of this breakthrough


The more the molecular structure of a supercooled liquid is studied, the more it clears up the scientific debate of whether there is a more state of water apart from the standard three- solid, liquid and gas.

The debate explores if at critical temperature if there exist two different states of liquid with unique physical properties such as density and compressibility.

Though before now the computer modelling of water is available for water under 41-degree Celcius, this method allows for the lower temperature of water to be studied.

This breakthrough does not solve the debate, but it offers more tools to check if the critical point for such behaviour exists in water.

Water is still an essential liquid, and a study of its properties are necessary to ascertain how liquid cold water can behave under certain conditions.

In nature, we have supercooled water drops in the upper atmosphere of the earth. Deciphering its nature could help understand more how ice form in the atmosphere.


References

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Nice ones more @greenrun, your blog is always amazing and fulfilling when ever I enter your blog then I am sure of getting something new about science.

Thanks for the compliment. I find it fulfilling too to write on those things.

Wow. Great piece of information. I just learnt more and new things.. I never knew

water can be a liquid and still cooled below 0-degree Celcius

Got to know that here and I'll research more on that.
I think the only thing I know about water is that it floats on water when blocked ice so I need to read more about water.

Education never stops. We never stop learning and steemit makes it rewarding. Thanks for dropping by.

Exactly. Life itself is a school. Thanks for sharing this also

Nice piece.. I couldn't have said it better, except that to note that ice MELTS at 32°F (0°C). In the freezing process, the smaller the (pure) water droplet, the colder it can become before it freezes spontaneously at around -40°C.

Thanks for this amazing article @greenrun

At standard pressure, the 0 degree celsius is like the equilibrium temperature. In other words, at exactly 0 degrees C, the solid and liquid phases coexist at an equilibrium. If you increase it you'd have a solid (freezing). If you decrease you'd have a liquid phase. You can toggle between the two by either increasing or decreasing. So ice and a cup of water can exist in the room indefinitely at thermal equilibrium.

I learnt of water existing in both liquid solid and gaseous state at the same time....how could u explain that for me..@greenrun

Thank you for this pieces it is educating.

I think that looks like a great idea for a post. Thanks for dropping by.

This is well detailed...no matter what, nothing can replace this natural component that the earth posses i.e Water.
Thanks for sharing.

Thank you. Water is important.

it requires forming a small nucleus called seed that enables the molecules to create crystals.

This method has been used over the years by inorganic chemist and organic chemist to synthesis/produce pure compounds which are then characterized by Xray crystallography. Crystallographers are seeding enthusiasts. Thanks for this article. It is more difficult than final year phase studies chemistry course. Hahaha

Synthesizing elements require those seeds. Thanks.

very nice photography..

I'm studying in C.E
but your content give much knowledge to know the Thermal Formation of water to any student. :)

I like C.E. How's school treating you? Have a wonderful day. Thanks

this is why i love to know more about science each degree matters :D

I agree with you @everblazing. Keep blazing the trail.

What's so different about you is the manipulation of words into molecules of interesting facts. He he he, i ain't no science student. Just tryna steal your brain.

Brains for sale.. Only 2 SBD :).

Lmao i'll pay 0.5sbd. SBD is really expensive now.

Send immediately.

Learning is endless. Please bring on more of this lectures. I just learnt this.

The more the molecular structure of a supercooled liquid is studied, the more it clears up the scientific debate of whether there is a more state of water apart from the standard three- solid, liquid and gas.

Thank you. More will definitely come.

How cold is the coldest bottle of drink or water you had last time? If it was so cold, it set your teeth on edge with ice on it, that would be said to be an icy drink. So you could have had a drink at temperature of 0-degree Celsius.

For this , Mine gives me brain freeze. Lol

Now this is magnificent, learning everyday

The scientists have this knowledge of supercooling water well below 0 degrees Celsius without its freezing. Scientists can push water to the -38 degrees Celsius, but the extreme crystallisation that follows makes studying its structural information as a liquid and getting reliable information impossible at below this point.

Thank you for visiting my blog.

Wow! Supercooling of liquids. That's really cool.
There's something I just thought about: Can it be possible to supercool water to absolute zero temperature (minus 273.15 degrees Celsius)?
Nice piece buddy

For now it's not possible. But in science impossible things have been known to happen.

Excellent

And moral of that post is...
Be supercool like water - as famous philosopher Bruce Lee once said.