Well, I think the answer is possibly that the lava formed into crystals based on the speed and conditions of its cooling. Natural crystals are extremely mathematical and stuff. But it is certainly curious that its called the Devil's Tower and also that the crystals are all six sided!
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The official story of the name was that it was misinterpreted or mistranslated, something like 'bad god's tower', so the name came to be. I would suggest that it was to keep curious christians scared away from the unique structure, so they won't ask questions!
I did consider the giant quartz formations that were found underground, maybe in Mexico, the math happening a few 'octaves' up from the usual quartz rock that we see, so that is something worth noting.
That IS interesting...